Autores
Sun Guohua
Título Exact solutions of the rigid rotor in the electric field
Tipo Revista
Sub-tipo JCR
Descripción International Journal of Quantum Chemistry
Resumen We first present a new constraint condition on the confluent Heun functionH(C)(alpha,beta,gamma,delta,eta;z) (beta,gamma >= 0,z is an element of [0, 1]) and then illustrate how to solve the rigid rotor in the electric field. We find its exact solutions unsolved previously through solving the Wronskian determinant. The present results compared with those by the perturbation methods are found to have a big difference for a large parametera. We also present 2D and 3D probability density distributions by choosing different angular momentum quantum numbersl. We observe that the original eigenvalues with degeneracy (2l + 1) are split into the (l + 1) state with approximate eigenvaluesl(l + 1) for smallabut largel.
Observaciones DOI 10.1002/qua.26336
Lugar New Jersey
País Estados Unidos
No. de páginas Article number e26336
Vol. / Cap. v. 120 no. 18
Inicio 2020-09-15
Fin
ISBN/ISSN